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71.
催化裂化汽油脱硫助剂TS-01的工业试验 总被引:3,自引:0,他引:3
中国石油化工股份有限公司九江分公司在I套催化裂化装置进行了TS—0l催化裂化汽油脱硫双功能助剂的工业应用。结果表明:TS—0l剂对催化裂化汽油有较好的脱硫效果。当TS—0l剂注入原料中的量为70μg/g时,对催化裂化汽油的硫脱除率约为20%;注入量为120μg/g时,硫脱除率可达到25%-30%。汽油中脱除的硫主要以硫化氢形态转移至于气、液化气中。TS—01剂对产品分布及产品其它质量无明显影响,该剂亦有良好的金属钝化效果。 相似文献
72.
Thecokesolutionlossreactionisoneofthemostimportanteffectsresultingincokepulverizinginblastfurnace .Thefactorswhichaffectreactionincludecokeporestructure ,micro crystalstructureonporewall ,thecontentandconstituentofminer als ,etc .Amongthesefactors ,theconstituentofmineralsisemphasizedallovertheworldinrecentyears .Buttheemphasisofmoststudieswasputontheeffectofalkalimetals (K ,Na)oncokesolutionlossreactionandtheeffectofotherelementswassel domreported[1-5] .Theeffectofthirteenmineralsoncokesolut… 相似文献
73.
介绍湛江东兴炼油厂的重整装置由200kt/a扩能至300kt/a中有关催化重整反应动力学模拟计算软件的应用、反应工艺技术的改造、装置标定的情况。结合装置实际情况,采用两段装填、两段混氢技术提升了装置的技术水平。标定结果表明,改造后的装置达到了预期目的。 相似文献
74.
VK Tzitzios V Georgakilas TN Angelidis 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(6):699-704
A study of nitrous oxide (N2O) reduction with methane (CH4) and propene (C3H6) in the presence of oxygen (5%) over Ag/Al2O3, Rh/Al2O3 and Ag–Rh/Al2O3 catalysts, with Ag and Rh loadings of 5 wt% and 0.05 wt% respectively, has been performed. From the results, it was observed that the Ag–Rh bimetallic catalyst was the most active for both nitrous oxide removal (more than 95%) and hydrocarbon oxidation. This high activity seems to be connected with a synergistic effect between Ag and Rh. The findings from X‐ray diffraction and X‐ray photoelectron spectroscopy studies showed also, that there were no strong interactions (eg alloying) between Ag and Rh. Copyright © 2005 Society of Chemical Industry 相似文献
75.
Yuanjing Zheng Anker Degn Jensen Jan Erik Johnsson 《Applied catalysis. B, Environmental》2005,60(3-4):253-264
The deactivation of a commercial type V2O5-WO3-TiO2 monolith catalyst under biomass combustion was studied at a full-scale grate-fired power plant burning straw/wood using a slip stream pilot scale reactor. The aerosols in the flue gas consisted of a mixture of potassium chloride and sulphate. Three catalyst elements were exposed at 350 °C, and one element was exposed at 250 °C for comparison. The catalyst activity was measured in the reactor at the exposure temperature by addition of NH3 and extra NO. The activity, in terms of a first-order rate constant, dropped by 52% after about 1140 h indicating a very fast deactivation compared to coal firing. It was also found that the reactor temperature was not of importance for the deactivation rate. SEM-EDX analysis showed that particle deposition and pore blocking contributed to the deactivation by decreasing the diffusion rate of NO and NH3 into the catalyst. However, potassium also penetrated into the catalyst wall and the resulting average K/V ratio in the catalyst structure was high enough (about 0.3–0.5) for a significant chemical deactivation. Chemisorption studies carried out in situ showed that the amount of chemisorbed NH3 on the catalyst decreased as a function of exposure time, which reveals that Brøndsted acid sites had reacted with potassium compounds and thereby rendered inactive. When washed by 0.5 M H2SO4 the regenerated catalyst regains a higher activity than that of the fresh catalyst at temperatures higher than 300 °C, but even though reactivation is possible, the deactivation rate appears too high for practical use of the SCR process in straw combustion. 相似文献
76.
Yi‐Hung Chen Ching‐Yuan Chang Wei‐Ling Su Chun‐Yu Chiu Yue‐Hwa Yu Pen‐Chi Chiang Chiung‐Fen Chang Je‐Lueng Shie Chyow‐San Chiou Sally IM Chiang 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(1):68-75
This study investigates the ozonation of CI Reactive Black 5 (RB5) by using the rotating packed bed (RPB) and completely stirred tank reactor (CSTR) as ozone contactors. The RPB, which provides high gravitational force by adjusting the rotational speed, was employed as a novel ozone contactor. The same ozone dosage was separately introduced into either the RPB or the CSTR for the investigation, while the experimental solution was continuously circulated within the apparatus consisting of the RPB and CSTR. The decolorization and mineralization efficiencies of RB5 in the course of ozonation are compared for these two methods. Moreover, the dissolved and off‐gas ozone concentrations were simultaneously monitored for the further analysis. As a result, the ozone mass transfer rate per unit volume of the RPB was significantly higher because of its higher mass transfer coefficient and gas–liquid concentration driving force. Furthermore, ozonation kinetics was found to be independent of the gravitational magnitude of an ozone gas–liquid contactor. Therefore, the results suggest employing RPBs as ozone‐contacting devices with the advantage of volume reduction. The experimental results, which can be used for further modeling of the ozonation process in the RPB, also show the requirement of correct design for the RPB. Consequently, the present study is useful for the understanding of practical application of RPBs. Copyright © 2004 Society of Chemical Industry 相似文献
77.
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79.
槽孔式水力驱动控制棒槽孔阻力系数实验研究 总被引:2,自引:0,他引:2
对槽孔式水力驱动控制棒槽对孔阻力系数进行了大量实验研究,获得了槽孔式水力驱动控制棒槽对孔阻力系数和其随槽对孔位移的变化规律,分析了槽对孔阻力系数与控制棒槽对孔结构参数之间的关系。结果表明:随槽对孔位移的增加,槽对孔阻力系数从某一较大的定值迅速降低到某一较小的定值,然后再迅速反回到初始的定值,形成一个对称的宽幅波谷;槽高使阻力系数曲线波谷幅宽发生变化,也使完全不重合段的阻力系数发生变化;随内套孔径的增大,阻力系数有所降低,其对阻力系数的影响也进一步减弱。孔径增大到一定程度,阻力系数基本不受孔径参数的影响。 相似文献
80.
中国先进研究堆导流箱流场的数值模拟 总被引:1,自引:1,他引:0
采用目前国内普遍使用的计算流体力学 (CFD)软件PHOENICS 3 2对中国先进研究堆不同结构的导流箱的三维流场进行数值模拟计算。结果表明 :导流箱入口导流板和导流筒能显著改善导流箱入口冷却剂的流动状况 ,获得入口冷却剂沿周向均匀分流的效果 ,达到显著减缓入口冷却剂对垂直辐照孔道导管及安全棒导管直接的横向水力冲刷的设计目的 相似文献